IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v13y2022i1d10.1038_s41467-022-32997-4.html
   My bibliography  Save this article

Small-molecule ionic liquid-based adhesive with strong room-temperature adhesion promoted by electrostatic interaction

Author

Listed:
  • Jun Zhang

    (Hunan University)

  • Wenxiang Wang

    (Hunan University)

  • Yan Zhang

    (Hunan University)

  • Qiang Wei

    (Hunan University)

  • Fei Han

    (Hunan University)

  • Shengyi Dong

    (Hunan University)

  • Dongqing Liu

    (National University of Defense Technology)

  • Shiguo Zhang

    (Hunan University)

Abstract

Low-molecular-weight adhesives (LMWAs) possess many unique features compared to polymer adhesives. However, fabricating LMWAs with adhesion strengths higher than those of polymeric materials is a significant challenge, mainly because of the relatively weak and unbalanced cohesion and interfacial adhesion. Herein, an ionic liquid (IL)-based adhesive with high adhesion strength is demonstrated by introducing an IL moiety into a Y-shaped molecule replete with hydrogen bonding (H-bonding) interactions. The IL moieties not only destroyed the rigid and ordered H-bonding networks, releasing more free groups to form hydrogen bonds (H-bonds) at the substrate/adhesive interface, but also provided electrostatic interactions that improved the cohesion energy. The synthesized IL-based adhesive, Tri-HT, could directly form thin coatings on various substrates, with high adhesion strengths of up to 12.20 MPa. Advanced adhesives with electrical conductivity, self-healing behavior, and electrically-controlled adhesion could also be fabricated by combining Tri-HT with carbon nanotubes.

Suggested Citation

  • Jun Zhang & Wenxiang Wang & Yan Zhang & Qiang Wei & Fei Han & Shengyi Dong & Dongqing Liu & Shiguo Zhang, 2022. "Small-molecule ionic liquid-based adhesive with strong room-temperature adhesion promoted by electrostatic interaction," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-32997-4
    DOI: 10.1038/s41467-022-32997-4
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-022-32997-4
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-022-32997-4?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Wei Zhang & Baohu Wu & Shengtong Sun & Peiyi Wu, 2021. "Skin-like mechanoresponsive self-healing ionic elastomer from supramolecular zwitterionic network," Nature Communications, Nature, vol. 12(1), pages 1-12, December.
    2. Chao Ma & Jing Sun & Bo Li & Yang Feng & Yao Sun & Li Xiang & Baiheng Wu & Lingling Xiao & Baimei Liu & Vladislav S. Petrovskii & Liu & Jinrui Zhang & Zili Wang & Hongyan Li & Lei Zhang & Jingjing Li , 2021. "Ultra-strong bio-glue from genetically engineered polypeptides," Nature Communications, Nature, vol. 12(1), pages 1-14, December.
    3. Dejin Jiao & Francisco Lossada & Jiaqi Guo & Oliver Skarsetz & Daniel Hoenders & Jin Liu & Andreas Walther, 2021. "Electrical switching of high-performance bioinspired nanocellulose nanocomposites," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
    4. Anjeza Beharaj & Ethan Z. McCaslin & William A. Blessing & Mark W. Grinstaff, 2019. "Sustainable polycarbonate adhesives for dry and aqueous conditions with thermoresponsive properties," Nature Communications, Nature, vol. 10(1), pages 1-7, December.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Xihao Pan & Rui Li & Wenyue Li & Wei Sun & Yiyang Yan & Xiaochen Xiang & Jinghua Fang & Youguo Liao & Chang Xie & Xiaozhao Wang & Youzhi Cai & Xudong Yao & Hongwei Ouyang, 2024. "Silk fibroin hydrogel adhesive enables sealed-tight reconstruction of meniscus tears," Nature Communications, Nature, vol. 15(1), pages 1-12, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Xiansheng Zhang & Hongwei Yan & Chongzhi Xu & Xia Dong & Yu Wang & Aiping Fu & Hao Li & Jin Yong Lee & Sheng Zhang & Jiahua Ni & Min Gao & Jing Wang & Jinpeng Yu & Shuzhi Sam Ge & Ming Liang Jin & Lil, 2023. "Skin-like cryogel electronics from suppressed-freezing tuned polymer amorphization," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    2. Chongrui Zhang & Xufei Liu & Jiang Gong & Qiang Zhao, 2023. "Liquid sculpture and curing of bio-inspired polyelectrolyte aqueous two-phase systems," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    3. Elvis K. Boahen & Baohai Pan & Hyukmin Kweon & Joo Sung Kim & Hanbin Choi & Zhengyang Kong & Dong Jun Kim & Jin Zhu & Wu Bin Ying & Kyung Jin Lee & Do Hwan Kim, 2022. "Ultrafast, autonomous self-healable iontronic skin exhibiting piezo-ionic dynamics," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    4. Jing Sun & Haonan He & Kelu Zhao & Wenhao Cheng & Yuanxin Li & Peng Zhang & Sikang Wan & Yawei Liu & Mengyao Wang & Ming Li & Zheng Wei & Bo Li & Yi Zhang & Cong Li & Yao Sun & Jianlei Shen & Jingjing, 2023. "Protein fibers with self-recoverable mechanical properties via dynamic imine chemistry," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    5. Rasool Nasseri & Negin Bouzari & Junting Huang & Hossein Golzar & Sarah Jankhani & Xiaowu (Shirley) Tang & Tizazu H. Mekonnen & Amirreza Aghakhani & Hamed Shahsavan, 2023. "Programmable nanocomposites of cellulose nanocrystals and zwitterionic hydrogels for soft robotics," Nature Communications, Nature, vol. 14(1), pages 1-15, December.
    6. FuYao Sun & LongFei Liu & Tong Liu & XueBin Wang & Qi Qi & ZuSheng Hang & Kai Chen & JianHua Xu & JiaJun Fu, 2023. "Vascular smooth muscle-inspired architecture enables soft yet tough self-healing materials for durable capacitive strain-sensor," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    7. Huanxi Zheng & Jing Li & Yongsen Zhou & Chao Zhang & Wanghuai Xu & Yajun Deng & Jiaqian Li & Shile Feng & Zhiran Yi & Xiaofeng Zhou & Xianglin Ji & Peng Shi & Zuankai Wang, 2022. "Electrically switched underwater capillary adhesion," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    8. Caicong Li & Jianxiang Cheng & Yunfeng He & Xiangnan He & Ziyi Xu & Qi Ge & Canhui Yang, 2023. "Polyelectrolyte elastomer-based ionotronic sensors with multi-mode sensing capabilities via multi-material 3D printing," Nature Communications, Nature, vol. 14(1), pages 1-14, December.
    9. Wenqian He & Meilin Wang & Guangkai Mei & Shiyong Liu & Abdul Qadeer Khan & Chao Li & Danyang Feng & Zihao Su & Lili Bao & Ge Wang & Enzhao Liu & Yutian Zhu & Jie Bai & Meifang Zhu & Xiang Zhou & Zunf, 2024. "Establishing superfine nanofibrils for robust polyelectrolyte artificial spider silk and powerful artificial muscles," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    10. Yongchun Liu & Ke Li & Juanhua Tian & Aiting Gao & Lihua Tian & Hao Su & Shuting Miao & Fei Tao & Hao Ren & Qingmin Yang & Jing Cao & Peng Yang, 2023. "Synthesis of robust underwater glues from common proteins via unfolding-aggregating strategy," Nature Communications, Nature, vol. 14(1), pages 1-15, December.
    11. Huating Ye & Baohu Wu & Shengtong Sun & Peiyi Wu, 2024. "Self-compliant ionic skin by leveraging hierarchical hydrogen bond association," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    12. Jing Chen & Yiyang Gao & Lei Shi & Wei Yu & Zongjie Sun & Yifan Zhou & Shuang Liu & Heng Mao & Dongyang Zhang & Tongqing Lu & Quan Chen & Demei Yu & Shujiang Ding, 2022. "Phase-locked constructing dynamic supramolecular ionic conductive elastomers with superior toughness, autonomous self-healing and recyclability," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    13. Tuo Deng & Dongxiu Gao & Xuemei Song & Zhipeng Zhou & Lixiao Zhou & Maixian Tao & Zexiu Jiang & Lian Yang & Lan Luo & Ankun Zhou & Lin Hu & Hongbo Qin & Mingyi Wu, 2023. "A natural biological adhesive from snail mucus for wound repair," Nature Communications, Nature, vol. 14(1), pages 1-18, December.
    14. Ran Yang & Xu Zhang & Binggang Chen & Qiuyan Yan & Jinghua Yin & Shifang Luan, 2023. "Tunable backbone-degradable robust tissue adhesives via in situ radical ring-opening polymerization," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    15. Jiqiang Wang & Baohu Wu & Peng Wei & Shengtong Sun & Peiyi Wu, 2022. "Fatigue-free artificial ionic skin toughened by self-healable elastic nanomesh," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    16. Yingkun Shi & Baohu Wu & Shengtong Sun & Peiyi Wu, 2023. "Aqueous spinning of robust, self-healable, and crack-resistant hydrogel microfibers enabled by hydrogen bond nanoconfinement," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    17. Sanwei Hao & Qingjin Fu & Lei Meng & Feng Xu & Jun Yang, 2022. "A biomimetic laminated strategy enabled strain-interference free and durable flexible thermistor electronics," Nature Communications, Nature, vol. 13(1), pages 1-13, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-32997-4. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.