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Chemically Modified Cyclodextrins: An Attractive Class of Supramolecular Hosts for the Development of Aqueous Biphasic Catalytic Processes

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  • Hervé Bricout

    ()
    (Univ Lille Nord de France, F-59000 Lille, France
    UArtois, UCCS, Faculté des Sciences Jean Perrin, Rue Jean Souvraz, SP 18-62307 Lens Cedex F-62300 Lens, France
    CNRS, UMR 8181, F-59650 Villeneuve d’Ascq, France)

  • Frédéric Hapiot

    ()
    (Univ Lille Nord de France, F-59000 Lille, France
    UArtois, UCCS, Faculté des Sciences Jean Perrin, Rue Jean Souvraz, SP 18-62307 Lens Cedex F-62300 Lens, France
    CNRS, UMR 8181, F-59650 Villeneuve d’Ascq, France)

  • Anne Ponchel

    ()
    (Univ Lille Nord de France, F-59000 Lille, France
    UArtois, UCCS, Faculté des Sciences Jean Perrin, Rue Jean Souvraz, SP 18-62307 Lens Cedex F-62300 Lens, France
    CNRS, UMR 8181, F-59650 Villeneuve d’Ascq, France)

  • Sébastien Tilloy

    ()
    (Univ Lille Nord de France, F-59000 Lille, France
    UArtois, UCCS, Faculté des Sciences Jean Perrin, Rue Jean Souvraz, SP 18-62307 Lens Cedex F-62300 Lens, France
    CNRS, UMR 8181, F-59650 Villeneuve d’Ascq, France)

  • Eric Monflier

    ()
    (Univ Lille Nord de France, F-59000 Lille, France
    UArtois, UCCS, Faculté des Sciences Jean Perrin, Rue Jean Souvraz, SP 18-62307 Lens Cedex F-62300 Lens, France
    CNRS, UMR 8181, F-59650 Villeneuve d’Ascq, France)

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    Abstract

    During these last years, cyclodextrins have contributed greatly to the development of catalytic processes in water. These cyclic oligosaccharides composed of 6(α), 7(β) or 8(γ) glucopyranose units improve the mass transfer in aqueous-organic two-phase systems and are useful compounds to design new catalysts. Thus, chemically modified cyclodextrins can be used to: (i) increase significantly the rate and selectivity of reactions catalyzed by water-soluble organometallic complexes, (ii) design new water-soluble ligands for aqueous organometallic catalysis, (iii) stabilize catalytically active noble metal nanoparticles in water and (iv) favour the dispersion and activation of the palladium on charcoal in water.

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    Bibliographic Info

    Article provided by MDPI, Open Access Journal in its journal Sustainability.

    Volume (Year): 1 (2009)
    Issue (Month): 4 (October)
    Pages: 924-945

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    Handle: RePEc:gam:jsusta:v:1:y:2009:i:4:p:924-945:d:6028

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    Related research

    Keywords: cyclodextrin; aqueous organometallic catalysis; nanoparticles; palladium on charcoal;

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