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The Influence of SnO 2 and Noble Metals on the Properties of TiO 2 for Environmental Sustainability

Author

Listed:
  • Evghenii Goncearenco

    (National Institute for Lasers, Plasma and Radiation Physics, 409 Atomistilor Str., 077125 Magurele, Romania
    These authors contributed equally to this work.)

  • Iuliana P. Morjan

    (National Institute for Lasers, Plasma and Radiation Physics, 409 Atomistilor Str., 077125 Magurele, Romania
    These authors contributed equally to this work.)

  • Claudiu Fleaca

    (National Institute for Lasers, Plasma and Radiation Physics, 409 Atomistilor Str., 077125 Magurele, Romania)

  • Elena Dutu

    (National Institute for Lasers, Plasma and Radiation Physics, 409 Atomistilor Str., 077125 Magurele, Romania)

  • Anca Criveanu

    (National Institute for Lasers, Plasma and Radiation Physics, 409 Atomistilor Str., 077125 Magurele, Romania)

  • Cristian Viespe

    (National Institute for Lasers, Plasma and Radiation Physics, 409 Atomistilor Str., 077125 Magurele, Romania)

  • Aurelian Catalin Galca

    (National Institute of Materials Physics, 405A Atomistilor Str., 077125 Magurele, Romania)

  • Adrian Valentin Maraloiu

    (National Institute of Materials Physics, 405A Atomistilor Str., 077125 Magurele, Romania)

  • Miruna S. Stan

    (Department of Biochemistry and Molecular Biology, Faculty of Biology, University of Bucharest, 91-95 Splaiul Independenţei Str., 050095 Bucharest, Romania)

  • Carmen Ioana Fort

    (Research Center of Electrochemistry and Non-Conventional Materials, Department of Chemical Engineering, Faculty of Chemistry and Chemical Engineering, “Babes-Bolyai” University, 11 Arany Janos Str., 400028 Cluj-Napoca, Romania)

  • Monica Scarisoreanu

    (National Institute for Lasers, Plasma and Radiation Physics, 409 Atomistilor Str., 077125 Magurele, Romania)

Abstract

In order to find solutions to current worldwide environmental problems, it is crucial to develop sustainable nanomaterials, ideally with multifunctional properties. Considering this, novel TiO 2 -SnO 2 @NMs (noble metals: Au and Ag) composites, for use as sustainable nanomaterials, were successfully prepared via a two-step synthesis process consisting of laser pyrolysis followed by the chemical impregnation of the collected materials with noble metals. The addition of SnO 2 favors the transformation of TiO 2 from a mixture with a majority Anatase phase to one with a Rutile phase majority. With consideration for their level of environmental toxicity, the features of the synthesized nanomaterials were structurally, morphologically, and optically described and assessed for environmental protection applications as gas sensors and photocatalysts. In the case of the Surface Acoustic Wave sensor, based on a pure TiO 2 nanopowder, a notable difference in the frequency shift was detected in comparison to the other examined sensors. All sensors responded to the CH 4 concentrations tested (0.02–0.1%). On the other hand, when methyl orange was photodegraded under visible light, the results obtained using NMs for decoration revealed that the photocatalytic activity of TiO 2 -SnO 2 @NMs was significantly improved compared to the TiO 2 -SnO 2 binary composite, which already has an enhanced photocatalytic activity, compared to pure TiO 2 . Overall, this work produces nanoparticles that exhibit better sensory and photocatalytic features, as well as higher levels of biocompatibility with skin cells, for use as eco-friendly nanomaterials for a sustainable future.

Suggested Citation

  • Evghenii Goncearenco & Iuliana P. Morjan & Claudiu Fleaca & Elena Dutu & Anca Criveanu & Cristian Viespe & Aurelian Catalin Galca & Adrian Valentin Maraloiu & Miruna S. Stan & Carmen Ioana Fort & Moni, 2024. "The Influence of SnO 2 and Noble Metals on the Properties of TiO 2 for Environmental Sustainability," Sustainability, MDPI, vol. 16(7), pages 1-24, March.
  • Handle: RePEc:gam:jsusta:v:16:y:2024:i:7:p:2904-:d:1367556
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