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Hydrophobic Coatings’ Efficiency and Limestones’ Resistance to Salt Crystallisation

Author

Listed:
  • Carla Lisci

    (HERCULES and IN2PAST Associated Laboratories, Institute for Advanced Studies and Research, University of Évora, Largo Marquês de Marialva 8, 7000-809 Évora, Portugal
    Geosciences Department, School of Sciences and Technology, University of Évora, Rua Romão Ramalho 59, 7000-671 Évora, Portugal)

  • Carlos Galhano

    (GEOBIOTEC and Earth Sciences Department, NOVA School of Science & Technology, 2829-516 Caparica, Portugal)

  • Joaquim Simão

    (GEOBIOTEC and Earth Sciences Department, NOVA School of Science & Technology, 2829-516 Caparica, Portugal)

  • Vera Pires

    (HERCULES and IN2PAST Associated Laboratories, Institute for Advanced Studies and Research, University of Évora, Largo Marquês de Marialva 8, 7000-809 Évora, Portugal
    LEM, Laboratório de Ensaios Mecânicos da Universidade de Évora, Rua Romão Ramalho 59, 7000-671 Évora, Portugal)

  • Fabio Sitzia

    (HERCULES and IN2PAST Associated Laboratories, Institute for Advanced Studies and Research, University of Évora, Largo Marquês de Marialva 8, 7000-809 Évora, Portugal
    Geosciences Department, School of Sciences and Technology, University of Évora, Rua Romão Ramalho 59, 7000-671 Évora, Portugal)

  • José Mirão

    (HERCULES and IN2PAST Associated Laboratories, Institute for Advanced Studies and Research, University of Évora, Largo Marquês de Marialva 8, 7000-809 Évora, Portugal
    Geosciences Department, School of Sciences and Technology, University of Évora, Rua Romão Ramalho 59, 7000-671 Évora, Portugal)

Abstract

Stone deterioration is significantly influenced by the process of salt crystallisation. The expansion of salt crystals on a porous framework exerts pressure on the solid fraction, causing the stone to deteriorate when the internal pressure of salt surpasses the stone’s strength. Protective coatings are employed to effectively hinder or substantially reduce the penetration of water and saline solutions. This study attempts to evaluate the effectiveness and long-term durability of limestones protected with hydrophobic coatings, focusing on their resistance to salt damage. The investigation followed the specifications set by the standard EN 12370:2019 and EN 14147:2003, which assesses the resistance of natural stone to salt crystallisation. The findings of this study indicate the conservation of physical–mechanical properties after ageing tests. In parallel, measurements of the static contact angle and the measurement of quality indexes revealed that the coatings maintained a certain level of hydrophobicity even after undergoing salt weathering tests, maintaining the good quality of the stones.

Suggested Citation

  • Carla Lisci & Carlos Galhano & Joaquim Simão & Vera Pires & Fabio Sitzia & José Mirão, 2024. "Hydrophobic Coatings’ Efficiency and Limestones’ Resistance to Salt Crystallisation," Sustainability, MDPI, vol. 16(2), pages 1-22, January.
  • Handle: RePEc:gam:jsusta:v:16:y:2024:i:2:p:816-:d:1321139
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