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TiO 2 /Arabic Gum for Degradation of Pollutants in Water

Author

Listed:
  • Anderson Lopes

    (Interdisciplinary Laboratory Advanced Materials (LIMAv), Federal of University of Piauí, Teresina 64049-550, PI, Brazil)

  • Francisca P. Araújo

    (Interdisciplinary Laboratory Advanced Materials (LIMAv), Federal of University of Piauí, Teresina 64049-550, PI, Brazil)

  • Dihego Damasceno

    (Interdisciplinary Laboratory Advanced Materials (LIMAv), Federal of University of Piauí, Teresina 64049-550, PI, Brazil)

  • Luzia M. C. Honório

    (Interdisciplinary Laboratory Advanced Materials (LIMAv), Federal of University of Piauí, Teresina 64049-550, PI, Brazil)

  • Alan I. S. Morais

    (Interdisciplinary Laboratory Advanced Materials (LIMAv), Federal of University of Piauí, Teresina 64049-550, PI, Brazil)

  • Luciano C. Almeida

    (Chemical Engineering Department, Federal University of Pernambuco, Recife 52171-900, PE, Brazil)

  • Ramón Peña Garcia

    (Academic Unit of Cabo de Santo Agostinho, Federal University of Rural Pernambuco, Cabo de Santo Agostinho 50670-901, PE, Brazil)

  • Edson C. Silva-Filho

    (Interdisciplinary Laboratory Advanced Materials (LIMAv), Federal of University of Piauí, Teresina 64049-550, PI, Brazil)

  • Marcelo B. Furtini

    (Interdisciplinary Laboratory Advanced Materials (LIMAv), Federal of University of Piauí, Teresina 64049-550, PI, Brazil)

  • Josy A. Osajima

    (Interdisciplinary Laboratory Advanced Materials (LIMAv), Federal of University of Piauí, Teresina 64049-550, PI, Brazil)

Abstract

Emerging contaminants and pollution are environmental problems threatening public health. Antibiotic ciprofloxacin and methylene blue dye are pollutants frequently detected in water systems worldwide. Photocatalysis is a process for water treatment. TiO 2 -based catalysts synthesized with natural gums show improved photocatalytic properties. Here, the sol–gel method synthesized TiO 2 /Arabic gum for photocatalytic performance. The innovation of this work was synthesized at 400 °C and investigated their photocatalytic proprieties using methylene blue and ciprofloxacin as model pollutants. XRD showed that the photocatalyst was in the anatase phase. The result showed that TiO 2 with a band gap of 3.29 eV was achieved at a calcination temperature of 400 °C. Corresponding FTIR results suggest only the existence of functional groups related to TiO 2 . The SEM and BET method characterization indicated that TiO 2 /Arabic gum were spherical-shaped nanoparticles arranged in clusters with a mesoporous structure, contributing to photocatalytic performance. In addition, photocatalytic studies showed that the methylene blue dye and ciprofloxacin antibiotic degradation rates reached 99% and 94% under UV light, respectively. The hole (h + ) and O H ⦁ radicals are essential in photodegradation. The synthesized material showed excellent photostability and maintained almost the same degradation percentage in the three consecutive cycles tested on the different pollutants. The TiO 2 /Arabic gum is an excellent candidate for future use in treating contaminants in aqueous media using photocatalysis. Therefore, TiO 2 /Arabic gum nanoparticles are a promising material for wastewater treatment.

Suggested Citation

  • Anderson Lopes & Francisca P. Araújo & Dihego Damasceno & Luzia M. C. Honório & Alan I. S. Morais & Luciano C. Almeida & Ramón Peña Garcia & Edson C. Silva-Filho & Marcelo B. Furtini & Josy A. Osajima, 2023. "TiO 2 /Arabic Gum for Degradation of Pollutants in Water," Sustainability, MDPI, vol. 15(22), pages 1-17, November.
  • Handle: RePEc:gam:jsusta:v:15:y:2023:i:22:p:15768-:d:1276720
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    Keywords

    dye; water treatment; oxide;
    All these keywords.

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