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Arsenic Adsorption and Desorption in Various Aqueous Media in the Nearshore Zone and Influencing Factors

Author

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  • Shuai Lu

    (Hebei Key Laboratory of Geological Resources and Environment Monitoring and Protection, Shijiazhuang 050021, China
    Key Laboratory of Groundwater Contamination and Remediation of Hebei Province and China Geological Survey, The Institute of Hydrogeology and Environmental Geology, Chinese Academy of Geological Sciences, Shijiazhuang 050061, China
    Hebei Center for Ecological and Environmental Geology Research, Hebei GEO University, Shijiazhuang 050031, China
    Hebei Province Collaborative Innovation Center for Sustainable Utilization of Water Resources and Optimization of Industrial Structure, Hebei GEO University, Shijiazhuang 050031, China)

  • Yimeng Yang

    (School of Water Resources and Environment, Hebei GEO University, Shijiazhuang 050031, China)

  • Xiaosi Su

    (Institute of Water Resources and Environment, Jilin University, Changchun 130021, China)

  • Kaining Yu

    (Hebei Center for Ecological and Environmental Geology Research, Hebei GEO University, Shijiazhuang 050031, China
    Hebei Province Collaborative Innovation Center for Sustainable Utilization of Water Resources and Optimization of Industrial Structure, Hebei GEO University, Shijiazhuang 050031, China
    Hebei Province Key Laboratory of Sustained Utilization and Development of Water Resources, Hebei GEO University, Shijiazhuang 050031, China
    School of Water Resources and Environment, Hebei GEO University, Shijiazhuang 050031, China)

  • Xinzhou Wang

    (Hebei Key Laboratory of Geological Resources and Environment Monitoring and Protection, Shijiazhuang 050021, China)

Abstract

A profound understanding of the adsorption and desorption characteristics of arsenic on various media in aqueous solutions is helpful for evaluating the behavior of arsenic in groundwater. In this study, the characteristics of arsenic adsorption and desorption on aqueous media including silty clay, fine sand, medium sand, and coarse sand with gravel from Shenyang Huangjia water source, China were investigated by batch experiments. The results showed that the aqueous media in the study area had a strong fixation ability for arsenic, and both physical and chemical adsorption of arsenic occurred. Among them, silty clay had the strongest adsorption capacity and the largest buffer capacity for arsenic. As the specific surface area (SSA) of the medium decreased, the adsorption capacity decreased, and the desorption capacity increased. There was an obvious positive correlation between the desorption capacity and adsorption capacity of arsenic, and the force of the adsorption process was larger than that of the desorption process. The pH, temperature, carbonate, and ionic strength all affected the arsenic adsorption and desorption, and adsorption of arsenic occurred mainly by obligate adsorption in the study area.

Suggested Citation

  • Shuai Lu & Yimeng Yang & Xiaosi Su & Kaining Yu & Xinzhou Wang, 2022. "Arsenic Adsorption and Desorption in Various Aqueous Media in the Nearshore Zone and Influencing Factors," Sustainability, MDPI, vol. 14(17), pages 1-17, September.
    • Handle: RePEc:gam:jsusta:v:14:y:2022:i:17:p:10935-:d:904277
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    References listed on IDEAS

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    1. Xuelian Xia & Yanguo Teng & Yuanzheng Zhai, 2022. "Biogeochemistry of Iron Enrichment in Groundwater: An Indicator of Environmental Pollution and Its Management," Sustainability, MDPI, vol. 14(12), pages 1-14, June.
    2. Athanasia K. Tolkou & George Z. Kyzas & Ioannis A. Katsoyiannis, 2022. "Arsenic(III) and Arsenic(V) Removal from Water Sources by Molecularly Imprinted Polymers (MIPs): A Mini Review of Recent Developments," Sustainability, MDPI, vol. 14(9), pages 1-16, April.
    3. Muhammad Bilal Shakoor & Nabeel Khan Niazi & Irshad Bibi & Mohammad Mahmudur Rahman & Ravi Naidu & Zhaomin Dong & Muhammad Shahid & Muhammad Arshad, 2015. "Unraveling Health Risk and Speciation of Arsenic from Groundwater in Rural Areas of Punjab, Pakistan," IJERPH, MDPI, vol. 12(10), pages 1-20, October.
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