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Non-Destructive Discrimination of Blue Inks on Suspected Documents through the Combination of Raman Spectroscopy and Chemometric Analysis

Author

Listed:
  • Sruthi Thiraviam Saravanan

    (Graduate Institute of Applied Science and Technology, National Taiwan University of Science and Technology, Taipei 10607, Taiwan
    Life Science Group, Scientific Research Division, National Synchrotron Radiation Research Center, Hsinchu 30076, Taiwan)

  • Jaysiva Ganesamurthi

    (Department of Chemical Engineering and Biotechnology, Research and Development Center for Smart Textile Technology, College of Engineering, National Taipei University of Technology, No.1, Section 3, Chung-Hsiao East Road, Taipei 10608, Taiwan)

  • Shen-Ming Chen

    (Department of Chemical Engineering and Biotechnology, Research and Development Center for Smart Textile Technology, College of Engineering, National Taipei University of Technology, No.1, Section 3, Chung-Hsiao East Road, Taipei 10608, Taiwan)

  • Tse-Wei Chen

    (Department of Chemical Engineering and Biotechnology, Research and Development Center for Smart Textile Technology, College of Engineering, National Taipei University of Technology, No.1, Section 3, Chung-Hsiao East Road, Taipei 10608, Taiwan
    Well Fore Special Wire Corporation, 10, Tzu-Chiang 7rd., Chung-Li Industrial Park, Taoyuan 320, Taiwan
    Department of Materials, Imperial College London, London SW7 2AZ, UK)

  • Chun-Jung Chen

    (Graduate Institute of Applied Science and Technology, National Taiwan University of Science and Technology, Taipei 10607, Taiwan
    Life Science Group, Scientific Research Division, National Synchrotron Radiation Research Center, Hsinchu 30076, Taiwan)

  • Keseven Lakshmanan

    (Nano-Architecture and Nano-Technology Laboratory, Graduate Institute of Applied Science and Technology, National Taiwan University of Science and Technology, Taipei 10607, Taiwan)

  • Partheeban Chinnamuthu

    (Nano-Architecture and Nano-Technology Laboratory, Graduate Institute of Applied Science and Technology, National Taiwan University of Science and Technology, Taipei 10607, Taiwan)

  • Xiaoheng Liu

    (Key Laboratory of Education Ministry for Soft Chemistry and Functional Materials, Nanjing University of Science and Technology, Nanjing 210094, China)

  • Ramachandran Balaji

    (Department of Electronics and Communication Engineering, Koneru Lakshmaiah Education Foundation, Vijayawada 522302, India)

Abstract

Increasingly sophisticated techniques for falsifying and forging legal documents demand non-destructive and accurate analysis methods. Researchers have extensively investigated ink discrimination through an interdisciplinary analysis involving Raman spectroscopy and chemometrics, which is now regarded as a leading forensic document analysis approach. In this study, a groundbreaking method was developed to identify the specific origin of blue-ink pens used in written documents. By employing Raman spectroscopy in conjunction with principal component analysis (PCA), we successfully differentiated between 45 different blue-ink pens used on various documents. The Raman spectroscopy analysis provided a visual examination of each blue ink’s unique Raman signature, and PCA was then applied to the processed spectral data. Moreover, we successfully distinguished highly similar ink types in documents through the combined use of Raman spectroscopy, Pearson’s correlation analysis, and a statistical approach (PCA).

Suggested Citation

  • Sruthi Thiraviam Saravanan & Jaysiva Ganesamurthi & Shen-Ming Chen & Tse-Wei Chen & Chun-Jung Chen & Keseven Lakshmanan & Partheeban Chinnamuthu & Xiaoheng Liu & Ramachandran Balaji, 2023. "Non-Destructive Discrimination of Blue Inks on Suspected Documents through the Combination of Raman Spectroscopy and Chemometric Analysis," J, MDPI, vol. 6(4), pages 1-8, September.
  • Handle: RePEc:gam:jjopen:v:6:y:2023:i:4:p:35-543:d:1247964
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