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Glassy states in attractive micellar systems

Author

Listed:
  • Mallamace, F.
  • Broccio, M.
  • Faraone, A.
  • Chen, W.R.
  • Chen, S.-H.

Abstract

Recent mode coupling theory (MCT) calculations show that in attractive colloids one may observe a new type of glass originating from clustering effects, as a result of the attractive interaction. This happens in addition to the known glass-forming mechanism due to cage effects in the hard sphere system. MCT also indicates that, within a certain volume fraction range, varying the external control parameter, the effective temperature, makes the glass-to-liquid-to-glass re-entrance and the glass-to-glass transitions possible. Here we present experimental evidence and details on this complex phase behavior in a three-block copolymer micellar system.

Suggested Citation

  • Mallamace, F. & Broccio, M. & Faraone, A. & Chen, W.R. & Chen, S.-H., 2004. "Glassy states in attractive micellar systems," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 339(1), pages 92-100.
  • Handle: RePEc:eee:phsmap:v:339:y:2004:i:1:p:92-100
    DOI: 10.1016/j.physa.2004.03.048
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