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Non-Markovian kinetic equations of dissociation and reversible reaction A+B⇄C in solutions

Author

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  • Doktorov, A.B.
  • Kipriyanov, A.A.

Abstract

A consistent many-particle approach has been used to derive integro-differential kinetic equations of a bulk reaction of dissociation in spatially non-uniform solutions in a hydrodynamic approximation with a realistic description of reactants structure and translational mobility. The detailed analysis of the memory function structure of this equation has been carried out, and a microscopic detailed balancing principle of the theory of migration accelerated reactions has been formulated. This has made it possible to formulate a macroscopic kinetic detailed balancing principle for non-Markovian dissociation and recombination kinetics. The non-Markovian kinetic equation of the reversible reaction A+B⇄C in spatially non-uniform systems is proposed. Thermodynamic detailed balancing principle is established.

Suggested Citation

  • Doktorov, A.B. & Kipriyanov, A.A., 2003. "Non-Markovian kinetic equations of dissociation and reversible reaction A+B⇄C in solutions," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 317(1), pages 41-62.
    • Handle: RePEc:eee:phsmap:v:317:y:2003:i:1:p:41-62
    DOI: 10.1016/S0378-4371(02)01324-9
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