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Violation of the electroneutrality condition in confined unsymmetrical electrolytes

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  • Lozada-Cassou, Marcelo
  • Olivares, Wilmer
  • Sulbarán, Belky
  • Jiang, Yu

Abstract

The three-point extension hypernetted chain-mean spherical theory of liquids is solved for a system formed by two charged plates immersed in a model unsymmetrical electrolyte. The charge on the plates is fixed as a function of the distance between the plates. The extent to which the local electroneutrality condition is not satisfied is studied. The plate-plate force is calculated and compared to that for confined symmetrical electrolytes.

Suggested Citation

  • Lozada-Cassou, Marcelo & Olivares, Wilmer & Sulbarán, Belky & Jiang, Yu, 1996. "Violation of the electroneutrality condition in confined unsymmetrical electrolytes," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 231(1), pages 197-206.
    • Handle: RePEc:eee:phsmap:v:231:y:1996:i:1:p:197-206
    DOI: 10.1016/0378-4371(95)00451-3
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