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Thermal hydrodynamic fluctuations of polymer globules

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  • Zvelindovsky, Andrei V.
  • Bedeaux, Dick

Abstract

Thermal excitations of polymer globules have been studied within the hydrodynamic correlation theory. The globule consists of the elastic and fluid components and is immersed into another fluid. Both fluids are considered to be compressible and Newtonian. The interaction between polymer and fluid components of the globule is described by an effective local friction force proportional to the difference between component velocities. The fluctuation inside the globule described by the linearized equations of Navier-Stokes and elasticity theory coupled by Darcy's law. In the case of perfect coupling at the interface the spectral densities of fluctuations are obtained using the fluctuation-dissipation theorem. The hydrodynamic correlation functions and the dynamical structure factor are found.

Suggested Citation

  • Zvelindovsky, Andrei V. & Bedeaux, Dick, 1995. "Thermal hydrodynamic fluctuations of polymer globules," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 222(1), pages 87-104.
  • Handle: RePEc:eee:phsmap:v:222:y:1995:i:1:p:87-104
    DOI: 10.1016/0378-4371(95)00286-3
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    References listed on IDEAS

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    1. Lisy, V. & Zatovsky, A.V. & Zvelindovsky, A.V., 1992. "Hydrodynamic fluctuations of spherical micelles and vesicles," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 183(3), pages 262-278.
    2. Jonathan Pincus, 1991. "The Australian Constitution: What Should Economists Do?," School of Economics and Public Policy Working Papers 1991-09, University of Adelaide, School of Economics and Public Policy.
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