IDEAS home Printed from https://ideas.repec.org/a/eee/phsmap/v168y1990i1p127-139.html
   My bibliography  Save this article

Partial order in phospholipid monolayers

Author

Listed:
  • Möhwald, H.
  • Kenn, R.M.
  • Degenhardt, D.
  • Kjaer, K.
  • Als-Nielsen, J.

Abstract

Phospholipid monolayers at the air/water interface are studied by fluorescence microscopy and by X-ray scattering techniques. Due to long-range electrostatic forces superlattices of domains of ordered lipid are observed. For lateral densities between an isotropic fluid (LE) and a nearly incompressible (S) phase, an additinal phase is detected and characterized. This phase (LC) exhibits long-range bond orientational and short-range positional order as expected for a hexatic phase. Yet it has lower than sixfold symmetry due to uniform tilt of the aliphatic tails with tilt angle decreasing on compression. Reflectivity data are in agreement with the view that the transition to the S phase involves head group ordering. At lower temperature, the LE phase is suppressed but the LC phase exhibits the same features as at room temperature with respect to lattice spacings, positional coherence length and tilt angle. These features appear to be rather general for many phospholipids and for single chain surfactants like fatty acids.

Suggested Citation

  • Möhwald, H. & Kenn, R.M. & Degenhardt, D. & Kjaer, K. & Als-Nielsen, J., 1990. "Partial order in phospholipid monolayers," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 168(1), pages 127-139.
    • Handle: RePEc:eee:phsmap:v:168:y:1990:i:1:p:127-139
    DOI: 10.1016/0378-4371(90)90364-X
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/037843719090364X
    Download Restriction: Full text for ScienceDirect subscribers only. Journal offers the option of making the article available online on Science direct for a fee of $3,000
    File URL: https://libkey.io/10.1016/0378-4371(90)90364-X?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. David Chapman, 1968. "Models of the working of a two-party electoral system Part II," Public Choice, Springer, vol. 5(1), pages 19-37, September.
    2. Joanny, J.-F. & De Gennes, P.G., 1987. "Bursting of a soap film in a viscous environment," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 147(1), pages 238-255.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Aharonson, Vered & Andelman, David & Zilman, Anton & Pincus, Philip A. & Raphaël, Elie, 1994. "Polymer adsorption at liquid/air interfaces under lateral pressure," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 204(1), pages 1-16.
    2. Bell, G.M. & Wilson, G.L., 1982. "Cooperative phenomena in monolayers at the water surface: A monomer-dimer lattice gas model," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 115(1), pages 85-100.
    3. Ruiz-Garcia, Jaime & Gámez-Corrales, Rogelio & Ivlev, Boris I., 1997. "Foam and cluster structure formation by latex particles at the air/water interface," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 236(1), pages 97-104.
    4. Kox, A.J. & Wiegel, F.W., 1978. "Statistical mechanics of a lipid monolayer," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 92(3), pages 466-474.
    5. Chowdhury, Debashish & Stauffer, Dietrich, 1992. "Bursting of soap films," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 186(1), pages 237-249.
    6. Kaye, R.D., 1981. "Orientational transitions in a dimer system," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 105(1), pages 347-356.
    7. Onuki, Akira, 1995. "Interface instability induced by an electric field in fluids," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 217(1), pages 38-52.
    8. Scott L. Feld & Bernard Grofman, 1991. "Incumbency Advantage, Voter Loyalty and the Benefit of the Doubt," Journal of Theoretical Politics, , vol. 3(2), pages 115-137, April.
    9. Elezović-Hadžić, Sunčica & Knežević, Milan, 1996. "Critical exponents of surface-interacting self-avoiding walks on a family of truncated n-simplex lattices," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 227(3), pages 213-233.
    10. Kawaguchi, Masami & Makino, Kyoko & Kato, Tadaya, 1997. "Viscous fingering patterns of silica suspensions in polymer solutions: effects of viscoelasticity and gravity," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 246(3), pages 385-398.
    11. Kumar, Sanjay & Singh, Yashwant, 1996. "On the critical behaviour of a surface interacting linear polymer chain," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 229(1), pages 61-71.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:phsmap:v:168:y:1990:i:1:p:127-139. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/physica-a-statistical-mechpplications/ .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.