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Steady state viscosity coefficients of charged colloidal systems

Author

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  • Dhont, J.K.G.

Abstract

For a dispersion containing small charged macro-particles, the steady-state shear-viscosity and other viscosity coefficients are calculated. The deformation of the electrical double layer around the macro-particles is taken into account upto first order in the Péclet number. The viscosity coefficients are expressed as integrals over the (non-equilibrium) structure factor, and are thus valid up to “higher orders” in volume fraction. The deformation of the static structure factor due to the shear-flow is also discussed. It turns out that the structure factor is non-analytic in the shear-rate for small shear-rates.

Suggested Citation

  • Dhont, J.K.G., 1987. "Steady state viscosity coefficients of charged colloidal systems," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 146(3), pages 541-581.
    • Handle: RePEc:eee:phsmap:v:146:y:1987:i:3:p:541-581
    DOI: 10.1016/0378-4371(87)90284-6
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