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Persistent organochlorine pesticides and polychlorinated biphenyls in intensive agricultural soils from North India

Author

Listed:
  • Bhupander KUMAR

    (National Reference Trace Organics Laboratory, Central Pollution Control Board, East Arjun Nagar, Delhi-110032, India)

  • Sanjay KUMAR

    (National Reference Trace Organics Laboratory, Central Pollution Control Board, East Arjun Nagar, Delhi-110032, India)

  • Richa GAUR

    (National Reference Trace Organics Laboratory, Central Pollution Control Board, East Arjun Nagar, Delhi-110032, India)

  • Gargi GOEL

    (National Reference Trace Organics Laboratory, Central Pollution Control Board, East Arjun Nagar, Delhi-110032, India)

  • Meenu MISHRA

    (National Reference Trace Organics Laboratory, Central Pollution Control Board, East Arjun Nagar, Delhi-110032, India)

  • Satish Kumar SINGH

    (National Reference Trace Organics Laboratory, Central Pollution Control Board, East Arjun Nagar, Delhi-110032, India)

  • Dev PRAKASH

    (National Reference Trace Organics Laboratory, Central Pollution Control Board, East Arjun Nagar, Delhi-110032, India)

  • Chandra Sekhar SHARMA

    (National Reference Trace Organics Laboratory, Central Pollution Control Board, East Arjun Nagar, Delhi-110032, India)

Abstract

Organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs) were determined in agricultural soils from the northern states of India. The average concentration of OCPs was 37.67 ± 0.33 ng/g (dry weight - DW) while HCHs alone accounted for 93% followed by DDT (4.27%) and endosulphan (2.51%). The α/γ ratio of HCH (< 0.01-8.64) reflects the use of technical as well as lindane formulations. The ratio of p,p'-DDT/p,p'-DDE (0.16) and o,p'-DDT/p,p'-DDT (< 0.01) indicates the contamination of soils with the past use of technical DDT. The mean concentrations of endosulphan and dieldrin were 0.95 ± 0.53 ng/g (DW)and 0.16 ± 0.07 ng/g (DW), respectively. The average concentration of PCBs was 13.44 ± 0.06 ng/g (DW). The toxic equivalency (TEQ) calculated using WHO 2005-TEFs ranged from 0.01 to 105.40 pg WHO 2005-TEQ/g (DW) with the mean of 13.78 ± 0.11 pg WHO 2005-TEQ/g (DW). PCB-105 (25%), PCB-114 (18%), and PCB-118 (18%) were the dominant congeners and accounted for 61% while a non ortho PCBs contributed only 18% to total DL-PCBs. The contamination of soils is a matter of concern but is not alarming because the observed levels were lower than those given by the Canadian soil quality guidelines.

Suggested Citation

  • Bhupander KUMAR & Sanjay KUMAR & Richa GAUR & Gargi GOEL & Meenu MISHRA & Satish Kumar SINGH & Dev PRAKASH & Chandra Sekhar SHARMA, 2011. "Persistent organochlorine pesticides and polychlorinated biphenyls in intensive agricultural soils from North India," Soil and Water Research, Czech Academy of Agricultural Sciences, vol. 6(4), pages 190-197.
  • Handle: RePEc:caa:jnlswr:v:6:y:2011:i:4:id:21-2011-swr
    DOI: 10.17221/21/2011-SWR
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