IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v7y2014i2p824-833d33071.html
   My bibliography  Save this article

Fractionation for Biodiesel Purification Using Supercritical Carbon Dioxide

Author

Listed:
  • Chao-Yi Wei

    (Department of Food Science, National Pingtung University of Science and Technology, Pingtung County 91201, Taiwan)

  • Tzou-Chi Huang

    (Department of Food Science, National Pingtung University of Science and Technology, Pingtung County 91201, Taiwan)

  • Zer-Ran Yu

    (Superwell Biotechnology Corporation, 465 Wenxin S. 2nd Road, Taichung City 40876, Taiwan)

  • Be-Jen Wang

    (Department of Food Science, National Chiayi University, Chiayi City 60004, Taiwan)

  • Ho-Hsien Chen

    (Department of Food Science, National Pingtung University of Science and Technology, Pingtung County 91201, Taiwan)

Abstract

In recent years, biodegradable and alternative biodiesel has attracted increased attention worldwide. Producing biodiesel from biomass involves critical separation and purification technology. Conventional technologies such as gravitational settling, decantation, filtration, water washing, acid washing, organic solvent washing and absorbent applications are inefficient, less cost effective and environmentally less friendly. In this study supercritical carbon dioxide (SC-CO 2 ) with few steps and a low environmental impact, was used for biodiesel fractionation from impure fatty acid methyl ester (FAME) solution mixes. The method is suitable for application in a variety of biodiesel production processes requiring subsequent stages of purification. The fractionation and purification was carried out using continuous SC-CO 2 fractionation equipment, consisting of three columns filled with stainless steel fragments. A 41.85% FAME content solution mix was used as the raw material in this study. Variables were a temperature range of 40–70 °C, pressure range of 10–30 MPa, SC-CO 2 flow rate range of 7–21 mL/min and a retention time range of 30–90 min. The Taguchi method was used to identify optimal operating conditions. The results show that a separated FAME content of 99.94% was verified by GC-FID under optimal fractionation conditions, which are a temperature of 40 °C of, a pressure level of 30MPa and a flow rate of 7 mL/min of SC-CO 2 for a retention time of 90 min.

Suggested Citation

  • Chao-Yi Wei & Tzou-Chi Huang & Zer-Ran Yu & Be-Jen Wang & Ho-Hsien Chen, 2014. "Fractionation for Biodiesel Purification Using Supercritical Carbon Dioxide," Energies, MDPI, vol. 7(2), pages 1-10, February.
  • Handle: RePEc:gam:jeners:v:7:y:2014:i:2:p:824-833:d:33071
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/7/2/824/pdf
    Download Restriction: no

    File URL: https://www.mdpi.com/1996-1073/7/2/824/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Marchetti, J.M. & Miguel, V.U. & Errazu, A.F., 2007. "Possible methods for biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 11(6), pages 1300-1311, August.
    2. Borugadda, Venu Babu & Goud, Vaibhav V., 2012. "Biodiesel production from renewable feedstocks: Status and opportunities," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 4763-4784.
    3. Rawat, I. & Ranjith Kumar, R. & Mutanda, T. & Bux, F., 2013. "Biodiesel from microalgae: A critical evaluation from laboratory to large scale production," Applied Energy, Elsevier, vol. 103(C), pages 444-467.
    4. Tariq, Muhammad & Ali, Saqib & Khalid, Nasir, 2012. "Activity of homogeneous and heterogeneous catalysts, spectroscopic and chromatographic characterization of biodiesel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(8), pages 6303-6316.
    5. Atadashi, I.M. & Aroua, M.K. & Aziz, A. Abdul, 2011. "Biodiesel separation and purification: A review," Renewable Energy, Elsevier, vol. 36(2), pages 437-443.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Bazgha Ijaz & Muhammad Asif Hanif & Umer Rashid & Muhammad Zubair & Zahid Mushtaq & Haq Nawaz & Thomas Shean Yaw Choong & Imededdine Arbi Nehdi, 2020. "High Vacuum Fractional Distillation (HVFD) Approach for Quality and Performance Improvement of Azadirachta indica Biodiesel," Energies, MDPI, vol. 13(11), pages 1-15, June.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Chakraborty, Rajat & Gupta, Abhishek.K. & Chowdhury, Ratul, 2014. "Conversion of slaughterhouse and poultry farm animal fats and wastes to biodiesel: Parametric sensitivity and fuel quality assessment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 120-134.
    2. Silitonga, A.S. & Atabani, A.E. & Mahlia, T.M.I. & Masjuki, H.H. & Badruddin, Irfan Anjum & Mekhilef, S., 2011. "A review on prospect of Jatropha curcas for biodiesel in Indonesia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(8), pages 3733-3756.
    3. Azad, A.K. & Rasul, M.G. & Khan, M.M.K. & Sharma, Subhash C. & Mofijur, M. & Bhuiya, M.M.K., 2016. "Prospects, feedstocks and challenges of biodiesel production from beauty leaf oil and castor oil: A nonedible oil sources in Australia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 302-318.
    4. Bhuiya, M.M.K. & Rasul, M.G. & Khan, M.M.K. & Ashwath, N. & Azad, A.K., 2016. "Prospects of 2nd generation biodiesel as a sustainable fuel—Part: 1 selection of feedstocks, oil extraction techniques and conversion technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 55(C), pages 1109-1128.
    5. Abdullah, Sharifah Hanis Yasmin Sayid & Hanapi, Nur Hanis Mohamad & Azid, Azman & Umar, Roslan & Juahir, Hafizan & Khatoon, Helena & Endut, Azizah, 2017. "A review of biomass-derived heterogeneous catalyst for a sustainable biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 1040-1051.
    6. Singh, Bhaskar & Guldhe, Abhishek & Rawat, Ismail & Bux, Faizal, 2014. "Towards a sustainable approach for development of biodiesel from plant and microalgae," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 216-245.
    7. Othman, Mohd Fahmi & Adam, Abdullah & Najafi, G. & Mamat, Rizalman, 2017. "Green fuel as alternative fuel for diesel engine: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 694-709.
    8. Mofijur, M. & Masjuki, H.H. & Kalam, M.A. & Hazrat, M.A. & Liaquat, A.M. & Shahabuddin, M. & Varman, M., 2012. "Prospects of biodiesel from Jatropha in Malaysia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 5007-5020.
    9. Tasić, Marija B. & Pinto, Luisa Fernanda Rios & Klein, Bruno Colling & Veljković, Vlada B. & Filho, Rubens Maciel, 2016. "Botryococcus braunii for biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 64(C), pages 260-270.
    10. Mukhtar, Ahmad & Saqib, Sidra & Mubashir, Muhammad & Ullah, Sami & Inayat, Abrar & Mahmood, Abid & Ibrahim, Muhammad & Show, Pau Loke, 2021. "Mitigation of CO2 emissions by transforming to biofuels: Optimization of biofuels production processes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
    11. Yang, Liuqing & Takase, Mohammed & Zhang, Min & Zhao, Ting & Wu, Xiangyang, 2014. "Potential non-edible oil feedstock for biodiesel production in Africa: A survey," Renewable and Sustainable Energy Reviews, Elsevier, vol. 38(C), pages 461-477.
    12. Chee Yoong Chooi & Jia Huey Sim & Shiau Foon Tee & Zhi Hua Lee, 2021. "Waste-Derived Green Nanocatalyst for Biodiesel Production: Kinetic-Mechanism Deduction and Optimization Studies," Sustainability, MDPI, vol. 13(11), pages 1-20, May.
    13. Bharathiraja, B. & Chakravarthy, M. & Kumar, R. Ranjith & Yuvaraj, D. & Jayamuthunagai, J. & Kumar, R. Praveen & Palani, S., 2014. "Biodiesel production using chemical and biological methods – A review of process, catalyst, acyl acceptor, source and process variables," Renewable and Sustainable Energy Reviews, Elsevier, vol. 38(C), pages 368-382.
    14. Mat Yasin, Mohd Hafizil & Mamat, Rizalman & Najafi, G. & Ali, Obed Majeed & Yusop, Ahmad Fitri & Ali, Mohd Hafiz, 2017. "Potentials of palm oil as new feedstock oil for a global alternative fuel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1034-1049.
    15. Guan, Qingqing & Shang, Hua & Liu, Jing & Gu, Junjie & Li, Bin & Miao, Rongrong & Chen, Qiuling & Ning, Ping, 2016. "Biodiesel from transesterification at low temperature by AlCl3 catalysis in ethanol and carbon dioxide as cosolvent: Process, mechanism and application," Applied Energy, Elsevier, vol. 164(C), pages 380-386.
    16. Fazal, Tahir & Mushtaq, Azeem & Rehman, Fahad & Ullah Khan, Asad & Rashid, Naim & Farooq, Wasif & Rehman, Muhammad Saif Ur & Xu, Jian, 2018. "Bioremediation of textile wastewater and successive biodiesel production using microalgae," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3107-3126.
    17. Mukhtar, Ahmad & Saqib, Sidra & Lin, Hongfei & Hassan Shah, Mansoor Ul & Ullah, Sami & Younas, Muhammad & Rezakazemi, Mashallah & Ibrahim, Muhammad & Mahmood, Abid & Asif, Saira & Bokhari, Awais, 2022. "Current status and challenges in the heterogeneous catalysis for biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 157(C).
    18. Bhuiya, M.M.K. & Rasul, M.G. & Khan, M.M.K. & Ashwath, N. & Azad, A.K. & Hazrat, M.A., 2016. "Prospects of 2nd generation biodiesel as a sustainable fuel – Part 2: Properties, performance and emission characteristics," Renewable and Sustainable Energy Reviews, Elsevier, vol. 55(C), pages 1129-1146.
    19. Jesús Andrés Tavizón-Pozos & Gerardo Chavez-Esquivel & Víctor Alejandro Suárez-Toriello & Carlos Eduardo Santolalla-Vargas & Oscar Abel Luévano-Rivas & Omar Uriel Valdés-Martínez & Alfonso Talavera-Ló, 2021. "State of Art of Alkaline Earth Metal Oxides Catalysts Used in the Transesterification of Oils for Biodiesel Production," Energies, MDPI, vol. 14(4), pages 1-24, February.
    20. Guldhe, Abhishek & Singh, Bhaskar & Mutanda, Taurai & Permaul, Kugen & Bux, Faizal, 2015. "Advances in synthesis of biodiesel via enzyme catalysis: Novel and sustainable approaches," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 1447-1464.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:7:y:2014:i:2:p:824-833:d:33071. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.