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The Global Inventory of Methane Hydrate in Marine Sediments: A Theoretical Approach

Author

Listed:
  • Klaus Wallmann

    (GEOMAR, Helmholtz Centre for Ocean Research Kiel, Wischhofstrasse 1-3, Kiel D-24148, Germany)

  • Elena Pinero

    (GEOMAR, Helmholtz Centre for Ocean Research Kiel, Wischhofstrasse 1-3, Kiel D-24148, Germany)

  • Ewa Burwicz

    (GEOMAR, Helmholtz Centre for Ocean Research Kiel, Wischhofstrasse 1-3, Kiel D-24148, Germany)

  • Matthias Haeckel

    (GEOMAR, Helmholtz Centre for Ocean Research Kiel, Wischhofstrasse 1-3, Kiel D-24148, Germany)

  • Christian Hensen

    (GEOMAR, Helmholtz Centre for Ocean Research Kiel, Wischhofstrasse 1-3, Kiel D-24148, Germany)

  • Andrew Dale

    (GEOMAR, Helmholtz Centre for Ocean Research Kiel, Wischhofstrasse 1-3, Kiel D-24148, Germany)

  • Lars Ruepke

    (GEOMAR, Helmholtz Centre for Ocean Research Kiel, Wischhofstrasse 1-3, Kiel D-24148, Germany)

Abstract

The accumulation of methane hydrate in marine sediments is controlled by a number of physical and biogeochemical parameters including the thickness of the gas hydrate stability zone (GHSZ), the solubility of methane in pore fluids, the accumulation of particulate organic carbon at the seafloor, the kinetics of microbial organic matter degradation and methane generation in marine sediments, sediment compaction and the ascent of deep-seated pore fluids and methane gas into the GHSZ. Our present knowledge on these controlling factors is discussed and new estimates of global sediment and methane fluxes are provided applying a transport-reaction model at global scale. The modeling and the data evaluation yield improved and better constrained estimates of the global pore volume within the modern GHSZ ( ≥ 44 × 10 15 m 3 ), the Holocene POC accumulation rate at the seabed (~1.4 × 10 14 g yr −1 ), the global rate of microbial methane production in the deep biosphere (4−25 × 10 12 g C yr −1 ) and the inventory of methane hydrates in marine sediments ( ≥ 455 Gt of methane-bound carbon).

Suggested Citation

  • Klaus Wallmann & Elena Pinero & Ewa Burwicz & Matthias Haeckel & Christian Hensen & Andrew Dale & Lars Ruepke, 2012. "The Global Inventory of Methane Hydrate in Marine Sediments: A Theoretical Approach," Energies, MDPI, vol. 5(7), pages 1-50, July.
  • Handle: RePEc:gam:jeners:v:5:y:2012:i:7:p:2449-2498:d:18876
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    References listed on IDEAS

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    1. Antje Boetius & Katrin Ravenschlag & Carsten J. Schubert & Dirk Rickert & Friedrich Widdel & Armin Gieseke & Rudolf Amann & Bo Barker Jørgensen & Ursula Witte & Olaf Pfannkuche, 2000. "A marine microbial consortium apparently mediating anaerobic oxidation of methane," Nature, Nature, vol. 407(6804), pages 623-626, October.
    2. Klaus Wallmann & Erwin Suess & Graham H. Westbrook & Gisela Winckler & Maria B. Cita, 1997. "Salty brines on the Mediterranean sea floor," Nature, Nature, vol. 387(6628), pages 31-32, May.
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    Cited by:

    1. Ouyang, Qian & Pandey, Jyoti Shanker & von Solms, Nicolas, 2022. "Insights into multistep depressurization of CH4/CO2 mixed hydrates in unconsolidated sediments," Energy, Elsevier, vol. 260(C).
    2. Hongsheng Dong & Lunxiang Zhang & Jiaqi Wang, 2022. "Formation, Exploration, and Development of Natural Gas Hydrates," Energies, MDPI, vol. 15(16), pages 1-4, August.
    3. Döpke, Lena-Katharina & Requate, Till, 2014. "The economics of exploiting gas hydrates," Energy Economics, Elsevier, vol. 42(C), pages 355-364.
    4. Mandeep R. Pandey & Jeffrey A. Priest & Jocelyn L. Hayley, 2022. "The Influence of Particle Size and Hydrate Formation Path on the Geomechanical Behavior of Hydrate Bearing Sands," Energies, MDPI, vol. 15(24), pages 1-23, December.
    5. Lee, Yohan & Deusner, Christian & Kossel, Elke & Choi, Wonjung & Seo, Yongwon & Haeckel, Matthias, 2020. "Influence of CH4 hydrate exploitation using depressurization and replacement methods on mechanical strength of hydrate-bearing sediment," Applied Energy, Elsevier, vol. 277(C).
    6. Maria De La Fuente & Sandra Arndt & Héctor Marín-Moreno & Tim A. Minshull, 2022. "Assessing the Benthic Response to Climate-Driven Methane Hydrate Destabilisation: State of the Art and Future Modelling Perspectives," Energies, MDPI, vol. 15(9), pages 1-32, May.
    7. Mahboubeh Rahmati-Abkenar & Milad Alizadeh & Marcelo Ketzer, 2021. "A New Dynamic Modeling Approach to Predict Microbial Methane Generation and Consumption in Marine Sediments," Energies, MDPI, vol. 14(18), pages 1-17, September.
    8. Luís Bernardes & Júlio Carneiro & Pedro Madureira & Filipe Brandão & Cristina Roque, 2015. "Determination of Priority Study Areas for Coupling CO2 Storage and CH 4 Gas Hydrates Recovery in the Portuguese Offshore Area," Energies, MDPI, vol. 8(9), pages 1-17, September.
    9. Fatima Doria Benmesbah & Livio Ruffine & Pascal Clain & Véronique Osswald & Olivia Fandino & Laurence Fournaison & Anthony Delahaye, 2020. "Methane Hydrate Formation and Dissociation in Sand Media: Effect of Water Saturation, Gas Flowrate and Particle Size," Energies, MDPI, vol. 13(19), pages 1-21, October.
    10. Ewa Burwicz & Lars Rüpke, 2019. "Thermal State of the Blake Ridge Gas Hydrate Stability Zone (GHSZ)—Insights on Gas Hydrate Dynamics from a New Multi-Phase Numerical Model," Energies, MDPI, vol. 12(17), pages 1-24, September.

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