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Irreversibility and entropy production in transport phenomena, IV: Symmetry, integrated intermediate processes and separated variational principles for multi-currents

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  • Suzuki, Masuo

Abstract

The mechanism of entropy production in transport phenomena is discussed again by emphasizing the role of symmetry of non-equilibrium states and also by reformulating Einstein’s theory of Brownian motion to derive entropy production from it. This yields conceptual reviews of the previous papers [M. Suzuki, Physica A 390 (2011) 1904; 391 (2012) 1074; 392 (2013) 314]. Separated variational principles of steady states for multi external fields {Xi} and induced currents {Ji} are proposed by extending the principle of minimum integrated entropy production found by the present author for a single external field. The basic strategy of our theory on steady states is to take in all the intermediate processes from the equilibrium state to the final possible steady states in order to study the irreversible physics even in the steady states. As an application of this principle, Gransdorff–Prigogine’s evolution criterion inequality (or stability condition) dXP≡∫dr∑iJidXi≤0 is derived in the stronger form dQi≡∫drJidXi≤0 for individual force Xi and current Ji even in nonlinear responses which depend on all the external forces {Xk} nonlinearly. This is called “separated evolution criterion”.

Suggested Citation

  • Suzuki, Masuo, 2013. "Irreversibility and entropy production in transport phenomena, IV: Symmetry, integrated intermediate processes and separated variational principles for multi-currents," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 392(19), pages 4279-4287.
  • Handle: RePEc:eee:phsmap:v:392:y:2013:i:19:p:4279-4287
    DOI: 10.1016/j.physa.2013.05.019
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