IDEAS home Printed from https://ideas.repec.org/a/eee/phsmap/v342y2004i1p40-47.html
   My bibliography  Save this article

Static heterogeneities in liquid water

Author

Listed:
  • Stanley, H.Eugene
  • Buldyrev, Sergey V.
  • Giovambattista, Nicolas

Abstract

The thermodynamic behavior of water seems to be closely related to static heterogeneities. These static heterogeneities are related to the local structure of water molecules, and when properly characterized, may offer an economical explanation of thermodynamic data. The key feature of liquid water is not so much that the existence of hydrogen bonds, first pointed out by Linus Pauling, but rather the local geometry of the liquid molecules is not spherical or oblong but tetrahedral. In the consideration of static heterogeneities, this local geometry is critical. Recent experiments suggested more than one phase of amorphous solid water, while simulations suggest that one of these phases is metastable with respect to another, so that in fact there are only two stable phases.

Suggested Citation

  • Stanley, H.Eugene & Buldyrev, Sergey V. & Giovambattista, Nicolas, 2004. "Static heterogeneities in liquid water," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 342(1), pages 40-47.
    • Handle: RePEc:eee:phsmap:v:342:y:2004:i:1:p:40-47
    DOI: 10.1016/j.physa.2004.06.045
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S037843710400812X
    Download Restriction: Full text for ScienceDirect subscribers only. Journal offers the option of making the article available online on Science direct for a fee of $3,000
    File URL: https://libkey.io/10.1016/j.physa.2004.06.045?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Osamu Mishima & H. Eugene Stanley, 1998. "Decompression-induced melting of ice IV and the liquid–liquid transition in water," Nature, Nature, vol. 392(6672), pages 164-168, March.
    2. Masakazu Matsumoto & Shinji Saito & Iwao Ohmine, 2002. "Molecular dynamics simulation of the ice nucleation and growth process leading to water freezing," Nature, Nature, vol. 416(6879), pages 409-413, March.
    3. Buldyrev, Sergey V. & Stanley, H.Eugene, 2003. "A system with multiple liquid–liquid critical points," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 330(1), pages 124-129.
    4. Osamu Mishima & H. Eugene Stanley, 1998. "The relationship between liquid, supercooled and glassy water," Nature, Nature, vol. 396(6709), pages 329-335, November.
    5. Stanley, H.E. & Buldyrev, S.V. & Giovambattista, N. & La Nave, E. & Scala, A. & Sciortino, F. & Starr, F.W., 2002. "Statistical physics and liquid water: “What matters”," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 306(C), pages 230-242.
    6. Franzese, Giancarlo & Eugene Stanley, H., 2002. "A theory for discriminating the mechanism responsible for the water density anomaly," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 314(1), pages 508-513.
    7. Stanley, H.Eugene & Barbosa, M.C & Mossa, S & Netz, P.A & Sciortino, F & Starr, F.W & Yamada, M, 2002. "Statistical physics and liquid water at negative pressures," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 315(1), pages 281-289.
    8. Jeffrey R. Errington & Pablo G. Debenedetti, 2001. "Relationship between structural order and the anomalies of liquid water," Nature, Nature, vol. 409(6818), pages 318-321, January.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Gorban, Alexander, 2007. "Order–disorder separation: Geometric revision," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 374(1), pages 85-102.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Stanley, H.Eugene & Andrade, José S. & Havlin, Shlomo & Makse, Hernán A. & Suki, Béla, 1999. "Percolation phenomena: a broad-brush introduction with some recent applications to porous media, liquid water, and city growth," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 266(1), pages 5-16.
    2. Stanley, H.E. & Kumar, P. & Xu, L. & Yan, Z. & Mazza, M.G. & Buldyrev, S.V. & Chen, S.-H. & Mallamace, F., 2007. "The puzzling unsolved mysteries of liquid water: Some recent progress," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 386(2), pages 729-743.
    3. Zhao Fan & Hajime Tanaka, 2024. "Microscopic mechanisms of pressure-induced amorphous-amorphous transitions and crystallisation in silicon," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    4. Kwang-Hua, Chu R., 2019. "Neutron scattering analysis of water’s glass transition and micropore collapse in amorphous solid water : Revisited," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 519(C), pages 18-21.
    5. Katrin Amann-Winkel & Kyung Hwan Kim & Nicolas Giovambattista & Marjorie Ladd-Parada & Alexander Späh & Fivos Perakis & Harshad Pathak & Cheolhee Yang & Tobias Eklund & Thomas J. Lane & Seonju You & S, 2023. "Liquid-liquid phase separation in supercooled water from ultrafast heating of low-density amorphous ice," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    6. Wiggins, Philippa M, 2002. "Water in complex environments such as living systems," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 314(1), pages 485-491.
    7. Stanley, H.E. & Buldyrev, S.V. & Franzese, G. & Havlin, S. & Mallamace, F. & Kumar, P. & Plerou, V. & Preis, T., 2010. "Correlated randomness and switching phenomena," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 389(15), pages 2880-2893.
    8. Rizzatti, Eduardo Osório & Gomes Filho, Márcio Sampaio & Malard, Mariana & Barbosa, Marco Aurélio A., 2019. "Waterlike anomalies in the Bose–Hubbard model," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 518(C), pages 323-330.
    9. Rui Shi & Anthony J. Cooper & Hajime Tanaka, 2023. "Impact of hierarchical water dipole orderings on the dynamics of aqueous salt solutions," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    10. Cardoso, Daniel Souza & Hernandes, Vinicius Fonseca & Nogueira, T.P.O. & Bordin, José Rafael, 2021. "Structural behavior of a two length scale core-softened fluid in two dimensions," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 566(C).
    11. Bumstead, M. & Arnold, B. & Turak, A., 2017. "Reproducing morphologies of disorderly self-assembling planar molecules with static and dynamic simulation methods by matching density," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 471(C), pages 301-314.
    12. Stephan Thaler & Julija Zavadlav, 2021. "Learning neural network potentials from experimental data via Differentiable Trajectory Reweighting," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
    13. Wei Wang & Shan Chen & Xuelong Liao & Rong Huang & Fengmei Wang & Jialei Chen & Yaxin Wang & Fei Wang & Huan Wang, 2023. "Regulating interfacial reaction through electrolyte chemistry enables gradient interphase for low-temperature zinc metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    14. Gorban, Alexander, 2007. "Order–disorder separation: Geometric revision," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 374(1), pages 85-102.
    15. Meijia Qiu & Peng Sun & Kai Han & Zhenjiang Pang & Jun Du & Jinliang Li & Jian Chen & Zhong Lin Wang & Wenjie Mai, 2023. "Tailoring water structure with high-tetrahedral-entropy for antifreezing electrolytes and energy storage at −80 °C," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    16. Cheolhee Yang & Marjorie Ladd-Parada & Kyeongmin Nam & Sangmin Jeong & Seonju You & Alexander Späh & Harshad Pathak & Tobias Eklund & Thomas J. Lane & Jae Hyuk Lee & Intae Eom & Minseok Kim & Katrin A, 2023. "Melting domain size and recrystallization dynamics of ice revealed by time-resolved x-ray scattering," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
    17. Kanth, Jampa Maruthi Pradeep & Anishetty, Ramesh, 2012. "Molecular mean field theory for liquid water," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 391(3), pages 439-455.
    18. Gautam, Arvind K. & Chandra, Avinash, 2020. "A computational study of excess properties for mW potential model of water in supercooled region," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 548(C).
    19. de Vasconcelos, Cláudia K.B. & Batista, Ronaldo J.C. & da Rocha Régis, McGlennon & Manhabosco, Taíse M. & de Oliveira, Alan B., 2016. "A simple model for solute–solvent separation through nanopores based on core-softened potentials," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 453(C), pages 184-193.
    20. Nogueira, T.P.O. & Bordin, José Rafael, 2022. "Patterns in 2D core-softened systems: From sphere to dumbbell colloids," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 605(C).

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:phsmap:v:342:y:2004:i:1:p:40-47. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/physica-a-statistical-mechpplications/ .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.