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Modeling the methanolysis of triglyceride catalyzed by immobilized lipase in a continuous-flow packed-bed reactor

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  • Tran, Dang-Thuan
  • Lin, Yi-Jan
  • Chen, Ching-Lung
  • Chang, Jo-Shu

Abstract

A Burkholderia lipase was immobilized on celite grafted with long alkyl groups. The immobilized lipase-catalyzed methanolysis of sunflower oil in a packed-bed reactor (PBR) follows the Ping Pong Bi Bi mechanism. The external mass transfer and enzymatic reaction that simultaneously occurred in the PBR were investigated via the mathematical models. The overall biodiesel production in the PBR was verified to work in an enzymatic reaction-limited regime. Triglyceride conversion and biodiesel yield were higher under a lower reactant feeding rate, while a larger amount of biocatalyst would be required to achieve the designated conversion rate if a higher reactant feeding rate was employed. The PBR can achieve nearly complete conversion of triglyceride at a biocatalyst bed height of 60cm (ca. 29g biocatalyst) and a flow rate of 0.1mlmin−1, whereas the biodiesel yield was lower than 67%, probably due to the positional specificity of Burkholderia lipase and the accumulation of glycerol.

Suggested Citation

  • Tran, Dang-Thuan & Lin, Yi-Jan & Chen, Ching-Lung & Chang, Jo-Shu, 2014. "Modeling the methanolysis of triglyceride catalyzed by immobilized lipase in a continuous-flow packed-bed reactor," Applied Energy, Elsevier, vol. 126(C), pages 151-160.
    • Handle: RePEc:eee:appene:v:126:y:2014:i:c:p:151-160
    DOI: 10.1016/j.apenergy.2014.03.082
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    References listed on IDEAS

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    1. Yan, Yunjun & Li, Xiang & Wang, Guilong & Gui, Xiaohua & Li, Guanlin & Su, Feng & Wang, Xiaofeng & Liu, Tao, 2014. "Biotechnological preparation of biodiesel and its high-valued derivatives: A review," Applied Energy, Elsevier, vol. 113(C), pages 1614-1631.
    2. Sharma, Y.C. & Singh, B., 2009. "Development of biodiesel: Current scenario," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(6-7), pages 1646-1651, August.
    3. Daroch, Maurycy & Geng, Shu & Wang, Guangyi, 2013. "Recent advances in liquid biofuel production from algal feedstocks," Applied Energy, Elsevier, vol. 102(C), pages 1371-1381.
    4. Santori, Giulio & Di Nicola, Giovanni & Moglie, Matteo & Polonara, Fabio, 2012. "A review analyzing the industrial biodiesel production practice starting from vegetable oil refining," Applied Energy, Elsevier, vol. 92(C), pages 109-132.
    5. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Mazaheri, Hossein, 2013. "A review on novel processes of biodiesel production from waste cooking oil," Applied Energy, Elsevier, vol. 104(C), pages 683-710.
    6. Liu, Chien-Hung & Huang, Chien-Chang & Wang, Yao-Wen & Lee, Duu-Jong & Chang, Jo-Shu, 2012. "Biodiesel production by enzymatic transesterification catalyzed by Burkholderia lipase immobilized on hydrophobic magnetic particles," Applied Energy, Elsevier, vol. 100(C), pages 41-46.
    7. Leung, Dennis Y.C. & Wu, Xuan & Leung, M.K.H., 2010. "A review on biodiesel production using catalyzed transesterification," Applied Energy, Elsevier, vol. 87(4), pages 1083-1095, April.
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    1. Budžaki, Sandra & Miljić, Goran & Tišma, Marina & Sundaram, Smitha & Hessel, Volker, 2017. "Is there a future for enzymatic biodiesel industrial production in microreactors?," Applied Energy, Elsevier, vol. 201(C), pages 124-134.
    2. Tran, Dang-Thuan & Chang, Jo-Shu & Lee, Duu-Jong, 2017. "Recent insights into continuous-flow biodiesel production via catalytic and non-catalytic transesterification processes," Applied Energy, Elsevier, vol. 185(P1), pages 376-409.
    3. Dutra, Luciana da Silva & Costa Cerqueira Pinto, Martina & Cipolatti, Eliane Pereira & Aguieiras, Erika Cristina G. & Manoel, Evelin Andrade & Greco-Duarte, Jaqueline & Guimarães Freire, Denise Maria , 2022. "How the biodiesel from immobilized enzymes production is going on: An advanced bibliometric evaluation of global research," Renewable and Sustainable Energy Reviews, Elsevier, vol. 153(C).
    4. Tran, Dang-Thuan & Chen, Ching-Lung & Chang, Jo-Shu, 2016. "Continuous biodiesel conversion via enzymatic transesterification catalyzed by immobilized Burkholderia lipase in a packed-bed bioreactor," Applied Energy, Elsevier, vol. 168(C), pages 340-350.

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