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Adsorption kinetics for CO2 on highly selective zeolites NaKA and nano-NaKA

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  • Cheung, Ocean
  • Bacsik, Zoltán
  • Liu, Qingling
  • Mace, Amber
  • Hedin, Niklas

Abstract

Carbon dioxide removal from flue gas via swing adsorption processes requires adsorbents with a high CO2 selectivity and capacity. These properties are particularly valuable to reduce the cost of carbon capture and storage (CCS). Zeolite NaKA was studied for its ability to selectively adsorb CO2 from flue gas, as we previously observed that zeolite NaKA, with a K+/(K++Na+) ratio of 17atomic%, was highly selective towards CO2 over N2 adsorption by tuning the size of the pore window apertures [1]. The reduced pore apertures may, however, retard the adsorption rate of CO2. Here, we studied the kinetics of CO2 adsorption on regularly sized zeolite NaKA and on nano-sized zeolite NaKA. We used in situ infrared (IR) spectroscopy and observed that CO2 physisorbed relatively rapidly. Density functional theory (DFT) was used for quantum chemical calculations, and the results indicated that CO2 molecules bridged across two or three Na+ ions in the samples with no or very small amount of K+. When more K+ ions are present the CO2 molecules no longer bridged across multiple metal ions and adopted an end-on configuration. The calculation showed a shift in the stretching vibration frequency of physisorbed CO2 as observed by IR spectroscopy. Nano-sized zeolite NaKA were synthesised and studied to improve the rate of CO2 adsorption, as the diffusion rate typically increases quadratically with decreasing particle size. Still, the CO2 adsorption rate on nano-sized zeolites NaA and NaKA did not increase significantly. For nano-sized zeolite NaA, we speculate that the absence of such an increased rate is an effect from a skin layer that had formed on the nano-sized zeolite NaA, a layer that was possibly related to intergrowths with extremely small crystals on the surface. The apparently slow adsorption kinetics of CO2 on nano-sized zeolite NaKA was more difficult to explain because it could relate to imperfections within the small crystals, remaining water, or other effects. Overall, the CO2 adsorption rates on zeolite NaKA crystals of different sizes were fast and relevant for the time scales required for adsorption based CCS processes, such as vacuum and temperature swing adsorption (VSA/TSA).

Suggested Citation

  • Cheung, Ocean & Bacsik, Zoltán & Liu, Qingling & Mace, Amber & Hedin, Niklas, 2013. "Adsorption kinetics for CO2 on highly selective zeolites NaKA and nano-NaKA," Applied Energy, Elsevier, vol. 112(C), pages 1326-1336.
    • Handle: RePEc:eee:appene:v:112:y:2013:i:c:p:1326-1336
    DOI: 10.1016/j.apenergy.2013.01.017
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    1. Hedin, Niklas & Andersson, Linnéa & Bergström, Lennart & Yan, Jinyue, 2013. "Adsorbents for the post-combustion capture of CO2 using rapid temperature swing or vacuum swing adsorption," Applied Energy, Elsevier, vol. 104(C), pages 418-433.
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    2. Wang, Meihong & Joel, Atuman S. & Ramshaw, Colin & Eimer, Dag & Musa, Nuhu M., 2015. "Process intensification for post-combustion CO2 capture with chemical absorption: A critical review," Applied Energy, Elsevier, vol. 158(C), pages 275-291.
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    4. Chen, S.J. & Fu, Y. & Huang, Y.X. & Tao, Z.C. & Zhu, M., 2016. "Experimental investigation of CO2 separation by adsorption methods in natural gas purification," Applied Energy, Elsevier, vol. 179(C), pages 329-337.
    5. Bacsik, Zoltán & Cheung, Ocean & Vasiliev, Petr & Hedin, Niklas, 2016. "Selective separation of CO2 and CH4 for biogas upgrading on zeolite NaKA and SAPO-56," Applied Energy, Elsevier, vol. 162(C), pages 613-621.
    6. Qasem, Naef A.A. & Ben-Mansour, Rached, 2018. "Energy and productivity efficient vacuum pressure swing adsorption process to separate CO2 from CO2/N2 mixture using Mg-MOF-74: A CFD simulation," Applied Energy, Elsevier, vol. 209(C), pages 190-202.
    7. Chen, S.J. & Zhu, M. & Fu, Y. & Huang, Y.X. & Tao, Z.C. & Li, W.L., 2017. "Using 13X, LiX, and LiPdAgX zeolites for CO2 capture from post-combustion flue gas," Applied Energy, Elsevier, vol. 191(C), pages 87-98.
    8. Gao, Jubao & Liu, Yida & Hoshino, Yu & Inoue, Gen, 2019. "Amine-containing nanogel particles supported on porous carriers for enhanced carbon dioxide capture," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    9. Ganapathy, Harish & Steinmayer, Sascha & Shooshtari, Amir & Dessiatoun, Serguei & Ohadi, Michael M. & Alshehhi, Mohamed, 2016. "Process intensification characteristics of a microreactor absorber for enhanced CO2 capture," Applied Energy, Elsevier, vol. 162(C), pages 416-427.
    10. Ganapathy, H. & Shooshtari, A. & Dessiatoun, S. & Alshehhi, M. & Ohadi, M., 2014. "Fluid flow and mass transfer characteristics of enhanced CO2 capture in a minichannel reactor," Applied Energy, Elsevier, vol. 119(C), pages 43-56.
    11. Chao, Cong & Deng, Yimin & Dewil, Raf & Baeyens, Jan & Fan, Xianfeng, 2021. "Post-combustion carbon capture," Renewable and Sustainable Energy Reviews, Elsevier, vol. 138(C).
    12. Pal, Animesh & Uddin, Kutub & Saha, Bidyut Baran & Thu, Kyaw & Kil, Hyun-Sig & Yoon, Seong-Ho & Miyawaki, Jin, 2020. "A benchmark for CO2 uptake onto newly synthesized biomass-derived activated carbons," Applied Energy, Elsevier, vol. 264(C).
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