IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v107y2013icp149-156.html
   My bibliography  Save this article

Towards biofuel combustion with an easily extruded clay as a natural catalyst

Author

Listed:
  • Tian, Zhen-Yu
  • Chafik, Tarik
  • Assebban, Mhamed
  • Harti, Sanae
  • Bahlawane, Naoufal
  • Mountapmbeme Kouotou, Patrick
  • Kohse-Höinghaus, Katharina

Abstract

The present work aims to investigate an innovative application of natural clay as a catalyst for biofuel combustion. The mineralogical, chemical, thermal and textural characterizations of the natural clay suggest an intrinsic catalytic potential without any prior treatment. The catalytic performance was studied with respect to the combustion of n-butanol as a representative biofuel using different forms of the natural clay: fine powder, pressed pellets and extruded honeycomb monoliths. No major difference was found among these forms regarding texture, morphology and stability. In terms of performance, this clay proved competitive relative to cobalt oxide spinel, which is one of the most reactive non-noble transition metal oxides. The significant amount of naturally occurring transition metals such as iron and some elements considered as promoters in the clay were proposed to account for the catalytic properties. A systematic investigation of the catalytic performance of the clay as a function of the equivalence ratio and of the total flow rate was performed using gas-phase FTIR spectroscopy. Increase of the equivalence ratio at a fixed flow rate yielded a lower catalytic performance toward n-butanol combustion producing a consequent fraction of carbon monoxide and ethylene. At a constant equivalence ratio of 0.6, the performance of the clay was not affected by increasing the total inlet flow rate up to 30sccm. These findings may initiate the development of a new catalyst for biofuel combustion based on relatively low-cost and abundantly available raw materials such as the natural clay investigated here.

Suggested Citation

  • Tian, Zhen-Yu & Chafik, Tarik & Assebban, Mhamed & Harti, Sanae & Bahlawane, Naoufal & Mountapmbeme Kouotou, Patrick & Kohse-Höinghaus, Katharina, 2013. "Towards biofuel combustion with an easily extruded clay as a natural catalyst," Applied Energy, Elsevier, vol. 107(C), pages 149-156.
  • Handle: RePEc:eee:appene:v:107:y:2013:i:c:p:149-156
    DOI: 10.1016/j.apenergy.2013.02.025
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261913001335
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.apenergy.2013.02.025?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Giakoumis, Evangelos G. & Dimaratos, Athanasios M. & Rakopoulos, Constantine D., 2011. "Experimental study of combustion noise radiation during transient turbocharged diesel engine operation," Energy, Elsevier, vol. 36(8), pages 4983-4995.
    2. Rakopoulos, C.D. & Dimaratos, A.M. & Giakoumis, E.G. & Rakopoulos, D.C., 2011. "Study of turbocharged diesel engine operation, pollutant emissions and combustion noise radiation during starting with bio-diesel or n-butanol diesel fuel blends," Applied Energy, Elsevier, vol. 88(11), pages 3905-3916.
    3. Kannan, G.R. & Karvembu, R. & Anand, R., 2011. "Effect of metal based additive on performance emission and combustion characteristics of diesel engine fuelled with biodiesel," Applied Energy, Elsevier, vol. 88(11), pages 3694-3703.
    4. Demirbas, Ayhan, 2011. "Competitive liquid biofuels from biomass," Applied Energy, Elsevier, vol. 88(1), pages 17-28, January.
    5. Agathou, Maria S. & Kyritsis, Dimitrios C., 2012. "Experimental investigation of bio-butanol laminar non-premixed flamelets," Applied Energy, Elsevier, vol. 93(C), pages 296-304.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Chen, Guanyi & Zhao, Liu & Qi, Yun, 2015. "Enhancing the productivity of microalgae cultivated in wastewater toward biofuel production: A critical review," Applied Energy, Elsevier, vol. 137(C), pages 282-291.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Fayyazbakhsh, Ahmad & Pirouzfar, Vahid, 2017. "Comprehensive overview on diesel additives to reduce emissions, enhance fuel properties and improve engine performance," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 891-901.
    2. Tan, Pi-qiang & Ruan, Shuai-shuai & Hu, Zhi-yuan & Lou, Di-ming & Li, Hu, 2014. "Particle number emissions from a light-duty diesel engine with biodiesel fuels under transient-state operating conditions," Applied Energy, Elsevier, vol. 113(C), pages 22-31.
    3. Giakoumis, Evangelos G. & Rakopoulos, Constantine D. & Dimaratos, Athanasios M. & Rakopoulos, Dimitrios C., 2013. "Exhaust emissions with ethanol or n-butanol diesel fuel blends during transient operation: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 17(C), pages 170-190.
    4. Pan, Suozhu & Cai, Kai & Cai, Min & Du, Chenbo & Li, Xin & Han, Weiqiang & Wang, Xin & Liu, Daming & Wei, Jiangjun & Fang, Jia & Bao, Xiuchao, 2021. "Experimental study on the cyclic variations of ethanol/diesel reactivity controlled compression ignition (RCCI) combustion in a heavy-duty diesel engine," Energy, Elsevier, vol. 237(C).
    5. Chang, Yu-Cheng & Lee, Wen-Jhy & Wu, Tser Son & Wu, Chang-Yu & Chen, Shui-Jen, 2014. "Use of water containing acetone–butanol–ethanol for NOx-PM (nitrogen oxide-particulate matter) trade-off in the diesel engine fueled with biodiesel," Energy, Elsevier, vol. 64(C), pages 678-687.
    6. Li, Bowen & Li, Yanfei & Liu, Haoye & Liu, Fang & Wang, Zhi & Wang, Jianxin, 2017. "Combustion and emission characteristics of diesel engine fueled with biodiesel/PODE blends," Applied Energy, Elsevier, vol. 206(C), pages 425-431.
    7. Jufang Zhang & Xiumin Yu & Zezhou Guo & Yinan Li & Jiahua Zhang & Dongjie Liu, 2022. "Study on Combustion and Emissions of a Spark Ignition Engine with Gasoline Port Injection Plus Acetone–Butanol–Ethanol (ABE) Direct Injection under Different Speeds and Loads," Energies, MDPI, vol. 15(19), pages 1-22, September.
    8. Ujor, Victor & Bharathidasan, Ashok Kumar & Cornish, Katrina & Ezeji, Thaddeus Chukwuemeka, 2014. "Feasibility of producing butanol from industrial starchy food wastes," Applied Energy, Elsevier, vol. 136(C), pages 590-598.
    9. Rinaldini, Carlo Alberto & Mattarelli, Enrico & Golovitchev, Valeri I., 2013. "Potential of the Miller cycle on a HSDI diesel automotive engine," Applied Energy, Elsevier, vol. 112(C), pages 102-119.
    10. Rezaei, Javad & Shahbakhti, Mahdi & Bahri, Bahram & Aziz, Azhar Abdul, 2015. "Performance prediction of HCCI engines with oxygenated fuels using artificial neural networks," Applied Energy, Elsevier, vol. 138(C), pages 460-473.
    11. Duan, Xiongbo & Xu, Zhengxin & Sun, Xingyu & Deng, Banglin & Liu, Jingping, 2021. "Effects of injection timing and EGR on combustion and emissions characteristics of the diesel engine fuelled with acetone–butanol–ethanol/diesel blend fuels," Energy, Elsevier, vol. 231(C).
    12. Wu, Shaohua & Yang, Wenming & Xu, Hongpeng & Jiang, Yu, 2019. "Investigation of soot aggregate formation and oxidation in compression ignition engines with a pseudo bi-variate soot model," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    13. Torregrosa, A.J. & Broatch, A. & García, A. & Mónico, L.F., 2013. "Sensitivity of combustion noise and NOx and soot emissions to pilot injection in PCCI Diesel engines," Applied Energy, Elsevier, vol. 104(C), pages 149-157.
    14. Li, Yuqiang & Chen, Yong & Wu, Gang & Liu, Jiangwei, 2018. "Experimental evaluation of water-containing isopropanol-n-butanol-ethanol and gasoline blend as a fuel candidate in spark-ignition engine," Applied Energy, Elsevier, vol. 219(C), pages 42-52.
    15. Liu, Haifeng & Li, Shanju & Zheng, Zunqing & Xu, Jia & Yao, Mingfa, 2013. "Effects of n-butanol, 2-butanol, and methyl octynoate addition to diesel fuel on combustion and emissions over a wide range of exhaust gas recirculation (EGR) rates," Applied Energy, Elsevier, vol. 112(C), pages 246-256.
    16. Campos-Fernández, Javier & Arnal, Juan M. & Gómez, Jose & Dorado, M. Pilar, 2012. "A comparison of performance of higher alcohols/diesel fuel blends in a diesel engine," Applied Energy, Elsevier, vol. 95(C), pages 267-275.
    17. Arbab, M.I. & Masjuki, H.H. & Varman, M. & Kalam, M.A. & Imtenan, S. & Sajjad, H., 2013. "Fuel properties, engine performance and emission characteristic of common biodiesels as a renewable and sustainable source of fuel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 22(C), pages 133-147.
    18. Zhao, Junfeng & Wang, Junmin, 2013. "Control-oriented multi-phase combustion model for biodiesel fueled engines," Applied Energy, Elsevier, vol. 108(C), pages 92-99.
    19. Luján, José Manuel & Serrano, José Ramón & Piqueras, Pedro & García-Afonso, Óscar, 2015. "Experimental assessment of a pre-turbo aftertreatment configuration in a single stage turbocharged diesel engine. Part 2: Transient operation," Energy, Elsevier, vol. 80(C), pages 614-627.
    20. Wu, Shaohua & Akroyd, Jethro & Mosbach, Sebastian & Brownbridge, George & Parry, Owen & Page, Vivian & Yang, Wenming & Kraft, Markus, 2020. "Efficient simulation and auto-calibration of soot particle processes in Diesel engines," Applied Energy, Elsevier, vol. 262(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:107:y:2013:i:c:p:149-156. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.